Jet ink composition, method and coated article

ABSTRACT

A jet ink composition, a jet ink coating method and a resulting jet ink coated article are all predicated upon the jet ink composition which includes in addition to a particulate pigment material and a solvent composition a resin composition. The resin composition includes an uncured silicone resin, an uncured epoxy resin and an uncured melamine resin. Upon thermal cure the uncured resin composition forms a cured resin composition with superior adhesion to substrates such as but not limited to glass substrates, ceramic substrates and metal oxide substrates.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of priority under 35 U.S.C. §119 ofU.S. Provisional Application Ser. No. 62/020,455 filed on Jul. 3, 2014the content of which is relied upon and incorporated herein by referencein its entirety.

BACKGROUND

Embodiments relate generally to jet ink compositions. More particularlyembodiments relate to enhanced performance jet ink compositions, relatedmethods and related coated articles.

Jet ink compositions that are used in jet ink printing processes arewell known materials that often provide precise and reproducible imageson porous substrates, such as but not limited to paper stock substrates.Unfortunately when applied to less porous substrates, such as but notlimited to glass substrates, jet ink image adhesion and opacity areoften compromised.

Thus, desirable are jet ink materials, jet ink coating processes and jetink coated articles with enhanced properties, such as but not limited toenhanced glass substrate adhesion properties and enhanced opacityproperties.

SUMMARY

Embodiments provide a jet ink composition, a method for coating andcuring an article while using the jet ink composition and the resultingcoated article that is coated with the cured jet ink composition.

Each of the foregoing jet ink composition, method for coating and curingthe article while using the jet ink composition and coated article thatis coated with the cured jet ink composition is predicated upon anuncured jet ink composition that comprises a pigment component, a resincomposition and a solvent composition that ultimately provide the curedjet ink composition with enhanced adhesion and enhanced opacity withrespect to a substrate surface (i.e., to provide the coated article), inparticular under circumstances where the substrate surface comprises aglass surface, a ceramic surface, a metal oxide surface, a metalsurface, or a polymeric surface.

In particular, an uncured resin composition within an uncured jet inkcomposition comprises an uncured silicone resin component (i.e., whichin accord with further description below may alternatively be describedas a silsesquioxane material component), an uncured epoxy resincomponent and an uncured melamine resin component.

And as well, a solvent composition within an uncured jet ink compositionin accordance with the embodiments comprises: (1)propylene-glycol-monomethyl-ether; (2) diethylene-glycol-dimethyl-ether;and (3) propylene-glycol-methyl-ether-acetate.

A particular jet ink composition in accordance with the embodimentsincludes a pigment material. This particular jet ink composition alsoincludes an uncured resin composition that further includes: (1) anuncured silicone resin component; (2) an uncured epoxy resin component;and (3) an uncured melamine resin component. This particular jet inkcomposition also includes a solvent composition that further includes:(1) propylene-glycol-monomethyl-ether; (2)diethylene-glycol-dimethyl-ether; and (3)propylene-glycol-methyl-ether-acetate.

A particular jet ink coating method in accordance with the embodimentsincludes coating upon a substrate an uncured jet ink compositionincluding: (1) a pigment material; (2) an uncured resin compositionincluding: (2a) an uncured silicone resin component; (2b) an uncuredepoxy resin component; and (2c) an uncured melamine resin component; and(3) a solvent composition including: (3a)propylene-glycol-monomethyl-ether; (3b) diethylene-glycol-dimethylether; and (3c) propylene-glycol-methyl-ether-acetate. This particularjet ink coating method also includes curing in-situ the uncured jet inkcomposition upon the substrate to form a cured jet ink compositioncoating upon the substrate.

A particular jet ink coated article in accordance with the embodimentsincludes a substrate. This particular jet ink coated article alsoincludes a cured coating located upon the substrate. The cured coatingincludes: (1) a pigment material; and (2) a cured resin bindercomposition binding the pigment material and comprising a cured siliconeresin component, a cured epoxy resin component and a cured melamineresin component. In some embodiments, the particular jet ink coatedarticle is incorporated into a consumer electronic product. The consumerelectronic component can have a housing having a front surface, a backsurface and side surfaces; electrical components provided at leastpartially internal to the housing, the electrical components includingat least a controller, a memory, and a display, the display beingprovided at or adjacent the front surface of the housing; and the jetink coated article of provided at or over the front surface of thehousing such that it is provided over the display, In some embodiments,the consumer electronic product is a mobile phone, portable mediaplayer, notebook computer or tablet computer.

BRIEF DESCRIPTION OF THE DRAWINGS

The objects, features and advantages of the embodiments are understoodwithin the context of the Detailed Description of the Non-LimitingEmbodiments, as set forth below. The Detailed Description of theNon-Limiting Embodiments is understood within the context of theaccompanying drawings, which form a material part of this disclosure,wherein:

FIG. 1 shows a thermal desorption gas chromatogram mass spectroscopy(GC/MS) spectrum of an uncured jet ink composition in accordance withthe embodiments.

FIG. 2 shows a Fourier transform infrared (FTIR) spectrum of an uncuredjet ink composition in accordance with the embodiments, with and withoutsolvent composition.

FIG. 3a shows a positive ionization electrospray mass spectrum for anuncured jet ink composition in accordance with the embodiments.

FIG. 3b shows a negative ionization electrospray mass spectrum for anuncured jet ink composition in accordance with the embodiments.

FIG. 4 shows a tabulation of experimentally determined properties andfunctional test criteria fulfilled by a cured jet ink composition coatedupon a cover lens substrate in accordance with the embodiments.

DETAILED DESCRIPTION

Embodiments provide an uncured jet ink composition, a method for coatingand curing an article while using the uncured jet ink composition andthe coated article that is coated with the uncured jet ink compositionand subsequently cured.

Each of the foregoing uncured jet ink composition, method for coatingand curing the article while using the uncured jet ink composition andcoated article that includes the cured jet ink composition is predicatedupon an uncured jet ink composition that comprises a pigment component,an uncured resin composition and a solvent composition that ultimatelyprovide the jet ink coated and cured article with enhanced adhesion andenhanced opacity with respect to the article surface, in particularunder circumstances where the article surface comprises a glass surface,a ceramic surface or a metal oxide surface.

I. The Uncured Jet Ink Composition in Accordance with the Embodiments

A first of the primary components of an uncured jet ink composition inaccordance with the embodiments is a pigment material that may comprise,but is not necessarily limited to, a carbon black particulate pigmentmaterial. Thus, in addition to a common black uncured jet inkcomposition, the embodiments also in general contemplate colored uncuredjet ink compositions, in particular comprising a color or colorsselected from the group including but not limited to red, green andblue, or alternatively from the group including but not limited toyellow, cyan and magenta. In general an uncured jet ink composition inaccordance with the embodiments does not discriminate with respect to acolor thereof, which is generally controlled by the color of the pigmentmaterial within the uncured jet ink composition.

A second of the primary components of an uncured jet ink composition inaccordance with the embodiments is an uncured resin composition thatincludes, but is not necessarily limited to: (1) an uncured siliconeresin component; (2) an uncured epoxy resin component; and (3) anuncured melamine resin component.

A third of the primary components of an uncured jet ink composition inaccordance with the embodiments is a solvent composition that includes,but is not necessarily limited to: (1)propylene-glycol-monomethyl-ether; (2) diethylene-glycol-dimethyl-ether;and (3) propylene-glycol-methyl-ether-acetate.

Further details relating to the three primary components of an embodieduncured jet ink composition in accordance with the embodiments are asfollows.

A pigment material (i.e., in particular a carbon black particulatepigment material) has a particle size from about 100 nanometers to about150 nanometers and is present at about 3 to about 5 weight percent ofthe uncured jet ink composition. A suitable carbon black particulatepigment material for an uncured jet ink composition in accordance withthe embodiments is generally commercially available. Several alternativecommercially available sources of carbon black particulate pigmentmaterial are not precluded in accordance with the embodiments.

As is understood by a person skilled in the art, nanometer sizedparticulate pigment materials generally have a higher absorption rate ofvisible light in comparison with larger size particulate pigmentmaterials, and may thus contribute to high optical density within acoated and cured jet ink composition in accordance with the embodiments,while maintaining a desirably low cured jet ink composition thickness.Nanometer sized carbon black particulate pigment materials also have aninhibited scattered reflection of visible light from the carbon blackparticulate pigment material surfaces, which increases the blackness ofa coated and cured jet ink composition in accordance with theembodiments.

An uncured silicone resin component within an uncured resin compositionwithin an uncured jet ink composition in accordance with the embodimentscomprises and may alternatively be defined as a silsesquioxane uncuredsilicone resin component, and more preferably (but not limited to) adivinyl-hexamethyl-octasila-silsesquioxane uncured silicone resincomponent (Vin2Me6Si8) whose chemical structure is illustrated in FIG. 1along with a thermal desorption gas chromatography mass spectrum of thedivinyl-hexamethyl-octasila-silsesquioxane uncured silicone resincomponent.

As is understood by a person skilled in the art, the Vin2Me6Si8silsesquioxane uncured silicone resin component whose chemical structureis illustrated in FIG. 1 is a condensation product of 2 molecules of avinyl-tri-substitutable silane and 6 molecules of amethyl-tri-substitutable silane. The tri-substitutable portions of theforegoing vinyl silane and methyl silane molecules may comprise, forexample and without limitation, substitutable chemical functionalityincluding but not limited to suitable halide functionality and suitablealkoxide functionality. Thus, suitable silane starting materials thatmay be used for preparing the silsesquioxane uncured silicone resincomponent whose chemical structure is illustrated in FIG. 1 may include,but are not limited to, vinyl-triethoxy-silane andmethyl-trimethoxy-silane. The silsesquioxane uncured silicone resincomponent whose chemical structure is illustrated in FIG. 1 is presentat about 15 to about 20 weight percent of an uncured jet ink compositionin accordance with the embodiments. The silsesquioxane uncured siliconeresin component whose chemical structure is illustrated in FIG. 1 isfurther characterized as a transparent viscous fluid having about 30% toabout 45% solids, a viscosity from about 10 to about 20 centipoise at 25C, a density from about 0.9 to about 1.0 gram/cm³ at 23 C, and a surfacetension from about 26 to about 29 dynes/cm.

A suitable uncured silicone resin component (i.e., including but notlimited to the Vin2Me6Si8 silsesquioxane whose chemical structure isillustrated in FIG. 1) for use within an uncured resin compositionwithin an uncured jet ink composition in accordance with the embodimentsis available from any of several commercial sources as an appropriatelydesignated uncured silicone resin. As noted above, the uncured siliconeresin component may alternatively be prepared in-situ from reaction ofan 1:3 ratio of an appropriate vinyl silane and an appropriate methylsilane.

An uncured epoxy resin component within an uncured resin compositionwithin an uncured jet ink composition in accordance with the embodimentshas a generally conventional molecular weight and is present at about0.5 to about 3.0 weight percent of the uncured jet ink composition inaccordance with the embodiments. Such an uncured epoxy resin componentmay derive from an uncured epoxy material selected from the groupincluding but not limited to bisphenol (i.e., A and F) based uncuredepoxy materials, novolak based uncured epoxy materials and aliphaticbased uncured epoxy materials. A suitable but not limiting uncured epoxyresin component is further characterized as a slightly white transparentviscous liquid having a viscosity from about 2500 to about 4500centipoise at 25 C, weight per epoxide (g/eq.) from about 160 to about170, and a density from about 1.15 to about 1.20 g/cm³ at 23 C.

Finally, an uncured melamine resin component within an uncured resincomposition within an uncured jet ink composition in accordance with theembodiments has a generally conventional molecular weight and is presentat about 1 to about 4 percent of the uncured jet ink composition inaccordance with the embodiments. Such an uncured melamine resincomponent may derive from generally conventional uncured melamine resinmaterials. A suitable but not limiting uncured melamine resin componentis characterized as a slightly yellow, transparent viscous fluid havinga solid content from about 75 to about 85 percent, a viscosity fromabout 3000 to about 4000 centipoise 23 C, and a density from about 1.1to about 1.5 g/cm³ at 23 C.

The uncured resin composition of an uncured jet ink composition inaccordance with the embodiments ensures adhesion of the particulatepigment material component (i.e., particularly a carbon blackparticulate pigment material component) to a substrate (i.e.,particularly a glass substrate). Moreover, the uncured resin compositionof an uncured jet ink composition assists when cured within the contextof meeting or surpassing environmental reliability test criteria commonwith respect to a particular end application of a jet ink coated andcured substrate in accordance with the embodiments. The uncured resincomposition of an uncured jet ink composition in accordance with theembodiments when cured may also ensure and provide additional functionalattributes to a cured jet ink composition coated article, such as butnot limited to solvent resistance and chemical resistance, and desirableelectrical resistivity characteristics.

To that end, nanometer sized carbon black particulate pigment materialstend to be more electrically conductive than larger sized carbon blackparticulate pigment materials. Therefore, the uncured resin componentswithin an uncured resin composition within an uncured jet inkcomposition in accordance with the embodiments are desirably able tofully encase the pigment material particles after curing, and preventpigment material particle coagulation and resulting loss of electricalresistivity within a cured jet ink composition in accordance with theembodiments.

An uncured jet ink composition in accordance with the embodiments may becharacterized as including a hybrid organic-inorganic resin composition.An inorganic uncured silicone resin component of an uncured resincomposition of an uncured jet ink composition in accordance with theembodiments is desirably selected to provide adequate adhesion to aglass substrate surface, adequate hardness of a cured jet ink coatingand adequate dimensional stability after high temperature bake (up toabout 250-280 C). An uncured epoxy resin component of an uncured resincomposition within an uncured jet ink composition in accordance with theembodiments provides resistance to alkali detergents that may be used incleaning the cured jet ink composition coating after curing. An uncuredmelamine resin component of an uncured jet ink resin composition withinan uncured jet ink composition in accordance with the embodiments isintended to provide adequate solvent and chemical resistance, andelectrical resistivity of the cured jet ink composition after coating.

Thus, in accordance with the foregoing an uncured resin compositionwithin an uncured jet ink composition in accordance with the embodimentsis coated upon a substrate using otherwise standard jet ink coatingapparatus and then desirably thermally cured at 150-200 C for greaterthan 10 min (i.e., presuming that the curing is undertaken in aconvection oven; shorter cure times may be accessible when using aninfrared oven).

Beyond the uncured silicone resin component, the uncured epoxy resincomponent and the uncured melamine resin component which are generallyintended as thermosetting resin components, the embodiments alsocontemplate addition of other resin components which may as appropriatebe thermosetting resin components or thermoplastic resin components, toachieve specific materials properties. Such thermoplastic resincomponents may include but are not limited to acrylic resin componentsand olefinic resin components.

With respect to the solvent composition within an uncured jet inkcomposition in accordance with the embodiments: (1)propylene-glycol-monomethyl-ether is present at about 30 to about 40weight percent; (2) diethylene-glycol-dimethyl-ether is present at about10 to about 13 weight percent; and (3)propylene-glycol-methyl-ether-acetate is present at about 10 to about 12weight percent. The three foregoing glycol solvents are regarded asgenerally conventional solvents that require no additional specificationand are readily sourced from any of several suppliers at an appropriatepurity level for use within an uncured jet ink composition in accordancewith the embodiments. Moreover, it is anticipated that the solventcomposition within an uncured jet ink composition in accordance with theembodiments may be characterized using a gas chromatography analysis at200 C.

In general in accordance with the embodiments, the solvent materials areselected to serve as a carrier for the pigment material particles and inparticular the carbon black pigment material particles, enabling thepigment material particles to be uniformly and smoothly ejected from ajet ink print head onto a non-porous substrate, such as but not limitedto a glass substrate, a ceramic substrate or a metal oxide substrate. Inaddition, the foregoing three solvent components also control thedrying, fluidic and wetting properties of the uncured jet inkcomposition, as well as ensuring that the uncured jet ink compositionviscosity and surface tension does not change with temperature, and thusmaintains stable printing performance (e.g., infrequent clogging ofprint head nozzles).

Beyond the foregoing primary components including the pigment component,the resin composition and the solvent composition, an uncured jet inkcomposition in accordance with the embodiments may also further comprisespecific additives that may be otherwise conventional or unconventionalwithin the context of uncured jet ink compositions. Such additionaladditives may include, but are not necessarily limited to: (1) adispersant that may be present at about 1.5 to about 3.5 weight percentand comprise a polyurethane and polymethylmethacrylate copolymermaterial; (2) a flow promoter that may be present at about 0.5 to about1 weight percent and comprise a polyether modifiedpoly-dimethyl-siloxane material; and (3) a resin strengthener that maybe present up to about 3 percent and comprise a conventionalcomposition.

A flow promoter additive in particular improves the wetting of theuncured jet ink composition onto a glass substrate, a ceramic substrateor a metal oxide substrate, thus preventing de-wetting of the uncuredjet ink composition from a substrate prior to curing. A flow promoterthat may be used within the context of an uncured jet ink composition inaccordance with the embodiments is generally commercially available.

On the other hand, a dispersant is intended to keep the pigment materialcomponent particles uniformly suspended even after being mixed into apaste and an uncured jet ink composition, and prevent coagulation orsedimentation. Coagulated pigment material component particles may clogjet ink nozzles, cause point defects when printed onto substrates anddramatically reduce electrical resistivity of a cured jet inkcomposition. Nanometer sized pigment material component particles aremore susceptible to coagulation in comparison with larger sized pigmentmaterial component particles, due to stronger van der Waal forces.

As noted above, a particular dispersant material uses a high molecularweight polyurethane and poly-methyl-methacrylate co-polymer material.This type of dispersant may have many anchor groups in the copolymermolecule to attach to pigment material particle surfaces, and thussurround a pigment material particle. The dispersant material co-polymermaterial molecules also have long polymer chains that provideinterstitial space for the uncured resin components and the solventmaterials in the uncured jet ink composition. A co-polymer dispersant asdescribed above must be compatible with an uncured resin composition anda solvent composition in accordance with the embodiments to ensure thatthe dispersant is fully dissolved, and that the dispersant polymerchains are fully extended. Such a full extension of dispersant polymerchains overcomes the van der Waals forces that attract the pigmentmaterial particles to each other, and ensures that pigment materialparticles do not coagulate either while in an uncured jet inkcomposition solution or after curing into a cured jet ink compositioncoating. A polyurethane and polymethyl-methacrylate copolymer dispersantthat is suitable for compatibility with an uncured resin composition inaccordance with the embodiments is commercially available.

An uncured jet ink composition in accordance with the embodiments may beprepared by mixing the foregoing components in any order, until auniform suspension of the uncured jet ink composition is obtained.Typically and preferably, the sum of the components is mixed andappropriately adjusted to provide an uncured jet ink composition thathas a viscosity from about 4 to about 6 centipoise at 25 degreesCelsius.

For reference purposes a Fourier transform infrared spectrum of anuncured jet ink composition in accordance with the embodiments is shownin FIG. 2, with and without solvent.

For reference purposes both a positive ionization electrosprayionization mass spectrum (FIG. 3a ) and a negative ionizationelectrospray ionization mass spectrum (FIG. 3b ) are also provided foran uncured jet ink composition in accordance with the embodiments.

The positive ionization electrospray ionization mass spectrum confirmsan identity of a flow promoter additive as apolyethylene-oxide-co-polydimethyl-siloxane copolymer. A random spacingof 44 Da (ethoxy) and 74 Da is typical ofethylene-oxide-co-dimethyl-siloxane copolymers, as is the observedisotopic distribution. The major distribution within the mass spectrumhas an approximate average molecular weight of 800 Da. A lesserdistribution within the mass spectrum has an average molecular weight of450 Da.

The negative ionization electrospray ionization mass spectrum confirmsthe presence of a series methyl and vinyl-functional silsesquioxanes. Inthat regard, the mass spacing within each series of 12 Da is typical ofthe R-group substitution of one methyl group for one vinyl groupsequentially. The isotopic distribution is typical of number of siliconatoms in the appropriate mass range corresponding to T6, T8, etc.

II. The Jet Ink Composition Coating Method in Accordance with theEmbodiments

A jet ink coating method in accordance with the embodiments parallelsgenerally the jet ink composition in accordance with the abovedescription. Thus, one first coats upon a substrate an uncured jet inkcomposition comprising: (1) a carbon black (or alternatively colored)pigment material; (2) an uncured resin composition comprising: (2a) anuncured silicone resin component; (2b) an uncured epoxy resin component;and (2c); an uncured melamine resin component (2c); and (3) a solventcomposition comprising: (3a) propylene-glycol-monomethyl-ether; (3b)diethylene-glycol-dimethyl-ether; and (3c)propylene-glycol-methyl-ether-acetate. One next cures in-situ theuncured jet ink composition upon the substrate to form a cured jet inkcomposition coating upon the substrate.

Within the embodiments the uncured jet ink composition is preferablythermally cured to form the cured jet ink composition coating. Suchthermal curing of the uncured jet ink composition to provide the curedjet ink composition coating is typically undertaken at a temperaturefrom about 160 to about 250 degrees centigrade, and for a time periodfrom about 1 to about 20 minutes, in an inert atmosphere. Such curingconditions may also depend on whether one uses a convection oven or aninfrared oven.

Consistent with aspects of the embodiments as discussed above, anuncured jet ink composition in accordance with the embodiments is coatedand cured upon a substrate selected from the group including but notlimited to a glass substrate, a ceramic substrate and a metal oxidesubstrate. Particular end product applications of such substrates arevaried.

The foregoing substrate selection options and uncured jet inkcomposition coating and thermal processing curing conditions are notintended to limit the embodiments with respect to any particularfunctional end result. Rather, the embodiments intend and expect thatalternative thermal processing curing conditions may be accessed torealize specific thermally cured jet ink composition coated substrates.

III. The Cured Jet Ink Composition Coated Article in Accordance with theEmbodiments

Following in sequence from the foregoing uncured jet ink composition andmethod for coating the foregoing jet ink composition to provide a curedjet ink composition coated article, is the cured jet ink compositioncoated article itself.

Such a cured jet ink coated article includes a substrate as well as thecured jet ink composition coating located upon the substrate. The curedcoating includes a pigment. The cured coating also includes a curedresin binder composition that further includes a cured silicone resincomponent, a cured epoxy resin component and a cured melamine resincomponent.

Desirably, within a coated article in accordance with the embodimentsthe substrate is selected from the group consisting of a glasssubstrate, a ceramic substrate and a metal oxide substrate.

Desirably, a cured coating in accordance with the embodiments has athickness from about 2 to about 6 microns.

Desirably, the coated article in accordance with the embodimentsexhibits an adhesion of the cured coating to the substrate that isgreater than or equal to 4B on a cross hatch adhesion test described asstandard test method.

Desirably the cured coating in accordance with the embodiments has anoptical density from about 3 to about 5.5.

Desirably within the cured coating in accordance with the embodimentsthe pigment component particles are regularly arranged.

Finally, the cured jet ink resin composition within the cured coatedarticle in accordance with the embodiments may be chemicallycharacterized using standard methodology.

In some embodiments the ink jet coated article can be incorporated intoa consumer electronic device. In some embodiments, the consumerelectronic component can have a housing having a front surface, a backsurface and side surfaces; electrical components provided at leastpartially internal to the housing, the electrical components includingat least a controller, a memory, and a display, the display beingprovided at or adjacent the front surface of the housing; and the jetink coated article of provided at or over the front surface of thehousing such that it is provided over the display. In some embodiments,the consumer electronic product is a mobile phone, portable mediaplayer, notebook computer or tablet computer.

IV. Experimental

For reference purposes, a tabulation of functional performancecharacteristic requirements of a cured jet ink composition coated upon aglass substrate is shown in FIG. 4. A cured jet ink composition coatedupon a glass substrate in accordance with the embodiments fulfills allof the tabulated functional performance characteristic requirements.

It will be apparent to those skilled in the art that variousmodifications and variations can be made without departing from thespirit or scope of the claims.

1-11. (canceled)
 12. A coated article comprising: a substrate; and acured coating located upon the substrate and comprising: a particulatepigment material; and a cured resin binder composition binding theparticulate pigment material and comprising a cured silicone resincomponent, a cured epoxy resin component and a cured melamine resincomponent.
 13. The coated article of claim 12 wherein the particulatepigment material comprises a carbon black particulate pigment material.14. The coated article of claim 12 wherein the substrate is selectedfrom the group consisting of a glass substrate, a ceramic substrate, ametal oxide substrate, a metal substrate, and a polymeric substrate. 15.The coated article of claim 13 wherein the cured coating has a thicknessfrom about 2 to about 6 microns.
 16. The coated article of claim 14wherein an adhesion of the cured coating to the substrate is greaterthan or equal to 4B on a cross hatch adhesion test.
 17. The coatedarticle of claim 13 wherein the cured coating has an optical densityfrom about 3 to about 5.5.
 18. The coated article of claim 13 whereinthe carbon black particulate pigment material particles are regularlyarranged.
 19. The coated article of claim 12 wherein: the coated articlecomprises a cover lens; and the coated article may be ultrasonicallycleaned with an aqueous alkali detergent solution absent discolorationof the cured coating or delamination or the cured coating from thesubstrate.
 20. A consumer electronic product, comprising: a housinghaving a front surface, a back surface and side surfaces; electricalcomponents provided at least partially internal to the housing, theelectrical components including at least a controller, a memory, and adisplay, the display being provided at or adjacent the front surface ofthe housing; and the coated article of claim 12 provided at or over thefront surface of the housing such that it is provided over the display.21. The consumer electronic product, wherein the consumer electronicproduct is a mobile phone, portable media player, notebook computer ortablet computer.